Efficient Aerobic Oxidation of 5-Hydroxymethylfurfural to 2, 5-Furandicarboxylic Acid over a Nanofiber Globule La-MnO<sub>2</sub> Catalyst

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چکیده

A La-MnO2 catalyst exhibited excellent performance in aerobic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Characterization the samples revealed that loose surface morphology and high oxygen species mobility facilitated HMF reaction. H2O was verified as a good solvent for formation FDCA because facilitation aldehyde group hydration generate carboxyl on molecule. 95.4% selectivity at 96.3% conversion achieved under mild conditions.

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ژورنال

عنوان ژورنال: Industrial & Engineering Chemistry Research

سال: 2021

ISSN: ['0888-5885', '1520-5045']

DOI: https://doi.org/10.1021/acs.iecr.0c05561